The preparation of organophosphorus ligand-modified SBA-15 for effective adsorption of Congo red and Reactive red 2

P,P-bis (2-oxooxazolidin-3-yl)- -(3-(triethoxysilyl)propyl)phosphinic amide (APTES-BOP)-modified SBA-15 (SBA-15-BOP) was prepared by a post-synthesis grafting method for the removal of anionic azo dyes from aqueous solutions. The properties of the prepared adsorbent were characterized by PXRD, FT-IR...

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Veröffentlicht in:RSC advances 2019-01, Vol.9 (24), p.13476-13485
Hauptverfasser: Zhang, Fan, Yang, Chuting, Li, Yi, Chen, Min, Hu, Sheng, Cheng, Haiming
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Sprache:eng
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Zusammenfassung:P,P-bis (2-oxooxazolidin-3-yl)- -(3-(triethoxysilyl)propyl)phosphinic amide (APTES-BOP)-modified SBA-15 (SBA-15-BOP) was prepared by a post-synthesis grafting method for the removal of anionic azo dyes from aqueous solutions. The properties of the prepared adsorbent were characterized by PXRD, FT-IR, SEM, TEM, nitrogen sorption, and elemental analysis. Adsorption equilibrium and adsorption kinetic studies demonstrated that the experimental data fitted well with the Langmuir isotherm model and pseudo-second-order model. According to Langmuir fitting, SBA-15-BOP showed high adsorption capacity for CR and RR2 dyes, with the maximum adsorption capacities of 518.1 mg g and 253.8 mg g , respectively. The thermodynamic study indicated that the adsorption processes of CR and RR2 dyes on SBA-15-BOP were spontaneous and exothermal. The prepared SBA-15-BOP can be a promising adsorbent for the removal of anionic dyes from aqueous solutions.
ISSN:2046-2069
2046-2069
DOI:10.1039/c9ra02287b