The preparation of organophosphorus ligand-modified SBA-15 for effective adsorption of Congo red and Reactive red 2
P,P-bis (2-oxooxazolidin-3-yl)- -(3-(triethoxysilyl)propyl)phosphinic amide (APTES-BOP)-modified SBA-15 (SBA-15-BOP) was prepared by a post-synthesis grafting method for the removal of anionic azo dyes from aqueous solutions. The properties of the prepared adsorbent were characterized by PXRD, FT-IR...
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Veröffentlicht in: | RSC advances 2019-01, Vol.9 (24), p.13476-13485 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | P,P-bis (2-oxooxazolidin-3-yl)-
-(3-(triethoxysilyl)propyl)phosphinic amide (APTES-BOP)-modified SBA-15 (SBA-15-BOP) was prepared by a post-synthesis grafting method for the removal of anionic azo dyes from aqueous solutions. The properties of the prepared adsorbent were characterized by PXRD, FT-IR, SEM, TEM, nitrogen sorption, and elemental analysis. Adsorption equilibrium and adsorption kinetic studies demonstrated that the experimental data fitted well with the Langmuir isotherm model and pseudo-second-order model. According to Langmuir fitting, SBA-15-BOP showed high adsorption capacity for CR and RR2 dyes, with the maximum adsorption capacities of 518.1 mg g
and 253.8 mg g
, respectively. The thermodynamic study indicated that the adsorption processes of CR and RR2 dyes on SBA-15-BOP were spontaneous and exothermal. The prepared SBA-15-BOP can be a promising adsorbent for the removal of anionic dyes from aqueous solutions. |
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ISSN: | 2046-2069 2046-2069 |
DOI: | 10.1039/c9ra02287b |