Ultrafine Pd nanoparticles loaded benzothiazole-linked covalent organic framework for efficient photocatalytic C-C cross-coupling reactions

We proposed a strategy that a benzothiazole-linked covalent organic framework ( TTT-COF ) was used as a substrate to prepare metal composite photocatalyst Pd NPs@TTT-COF . Firstly, benzothiazole linked TTT-COF exhibited superior chemical stability and photoresponse. Moreover, a finer particle size (2.01 nm) and more uniform distribution of Pd NPs were observed in Pd NPs@TTT-COF owing to the binding interaction between Pd NPs and S in benzothiazole groups. Pd NPs@TTT-COF exhibited superior efficiency and reusability in photocatalytic C-C cross-coupling reactions. Mechanism study suggested that photogenerated electrons and holes on TTT-COF played important roles in these reactions. Benzothiazole-linked covalent organic framework with characteristic properties loaded Pd nanoparticles for photocatalytic C-C cross-coupling reactions.