Direct use of 1,3-dienes for the allylation of ketones via catalytic hydroindation

Direct use of 1,3-dienes for the allylation of ketones via catalytic hydroindation

In this study, catalytically generated allylic indium from 1,3 dienes and InCl H was developed for use in the allylation of ketones. This protocol resulted in the unprecedented establishment of a successive combining of quaternary C-C bonds, which could then be applied to many types of ketones. Othe...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:RSC advances 2020-02, Vol.10 (10), p.6030-6034
Hauptverfasser: Suzuki, Itaru, Yagi, Kensuke, Miyamoto, Shinji, Shibata, Ikuya
Format: Artikel
Sprache:eng
Schlagworte:
Allyl compounds
Chemical reactions
Chemistry
Covalent bonds
Dienes
Ketones
Organic compounds
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In this study, catalytically generated allylic indium from 1,3 dienes and InCl H was developed for use in the allylation of ketones. This protocol resulted in the unprecedented establishment of a successive combining of quaternary C-C bonds, which could then be applied to many types of ketones. Other branched 1,3 dienes and vinyl cyclopropanes, could also be coupled with ketones in a reaction where CuH would not be applicable.
ISSN:2046-2069
2046-2069
DOI:10.1039/d0ra00853b