Crystal structure and Hirshfeld surface analysis of 2-amino-4-(4-meth-oxy-phen-yl)-6-oxo-1-phenyl-1,4,5,6-tetra-hydro-pyridine-3-carbo-nitrile

The central tetra-hydro-pyridine ring of the title compound, C H N O , adopts a screw-boat conformation. In the crystal, strong C-H⋯O and N-H⋯N hydrogen bonds form dimers with (14) and (12) ring motifs, respectively, between consecutive mol-ecules along the -axis direction. Inter-molecular N-H⋯O and...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2022-02, Vol.78 (Pt 3), p.330-335
Hauptverfasser: Asadov, Khammed A, Khrustalev, Victor N, Dobrokhotova, Ekaterina V, Akkurt, Mehmet, Huseynova, Afet T, Akobirshoeva, Anzurat A, Huseynov, Elnur Z
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Sprache:eng
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Zusammenfassung:The central tetra-hydro-pyridine ring of the title compound, C H N O , adopts a screw-boat conformation. In the crystal, strong C-H⋯O and N-H⋯N hydrogen bonds form dimers with (14) and (12) ring motifs, respectively, between consecutive mol-ecules along the -axis direction. Inter-molecular N-H⋯O and C-H⋯O hydrogen bonds connect these dimers, forming a three-dimensional network. C-H⋯π inter-actions and π-π stacking inter-actions contribute to the stabilization of the mol-ecular packing. A Hirshfeld surface analysis indicates that the contributions from the most prevalent inter-actions are H⋯H (47.1%), C⋯H/H⋯C (20.9%), O⋯H/H⋯O (15.3%) and N⋯H/H⋯N (11.4%).
ISSN:2056-9890
2056-9890
DOI:10.1107/S205698902200175X