Molecular Approach to Alkali-Metal Encapsulation by a Prussian Blue Analogue FeII/CoIII Cube in Aqueous Solution: A Kineticomechanistic Exchange Study

The preparation of a series of alkali-metal inclusion complexes of the molecular cube [{CoIII(Me3-tacn)}4{FeII(CN)6}4]4– (Me3-tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane), a mixed-valent Prussian Blue analogue bearing bridging cyanido ligands, has been achieved by following a redox-triggered self...

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Veröffentlicht in:	Inorganic chemistry 2021-12, Vol.60 (23), p.18407-18422
Hauptverfasser:	Gonzálvez, Miguel A, Bernhardt, Paul V, Font-Bardia, Mercè, Gallen, Albert, Jover, Jesús, Ferrer, Montserrat, Martínez, Manuel
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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