The combination of Al2O3 and BN for enhancing the thermal conductivity of PA12 composites prepared by selective laser sintering

A powder-based 3D printing technology, selective laser sintering (SLS), is a novel strategy of manufacturing complex components with specially tailored properties, including mechanical properties, as well as thermal and electrical conductivity. In this study, the effect of incorporating Al2O3 particles and BN plates on the thermal conductivity of PA12 composites was investigated. PA12 composite powders, which can be well applied to SLS, were prepared via a two-step approach to mixing. Morphology characteristics demonstrated that the fillers dispersed uniformly in the PA12 matrix, as expected. With 35 wt% Al2O3 and 15 wt% BN hybrid fillers, the tensile strength had the potential to reach 25.7 MPa, while the thermal conductivity could reach 1.05 W m−1 K−1, 275% higher than that of pure PA12. In addition, the study investigated the effects of filler content on the thermal stability and mechanical properties whilst analysing the melting and crystallisation behaviours of SLS components. The results demonstrate that these composites have favourable thermal stability and exhibit no severe deterioration in mechanical properties. The PA12 composites prepared in this work therefore illustrated vast potential in thermal management materials.