Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

N-Dealkylation of amines by metal oxo intermediates (M=O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.

Bibliographische Detailangaben

Veröffentlicht in:	Chemical science (Cambridge) 2021-11, Vol.12 (43), p.14494-14498
Hauptverfasser:	Xiang, Jing, Peng, Min, Pan, Yi, Luo, Li-Juan, Cheng, Shun-Cheung, Jin, Xin-Xin, Yiu, Shek-Man, Man, Wai-Lun, Ko, Chi-Chiu, Lau, Kai-Chung, Lau, Tai-Chu
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylamines Amines Chemistry Chemistry, Multidisciplinary Dealkylation Osmium Physical Sciences Science & Technology
Online-Zugang:	Volltext
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