Visible light-induced oxidative N -dealkylation of alkylamines by a luminescent osmium( vi ) nitrido complex

Visible light-induced oxidative N -dealkylation of alkylamines by a luminescent osmium( vi ) nitrido complex

N -Dealkylation of amines by metal oxo intermediates (MO) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N -dealkylation of various alkylamines by a luminescent osmium( vi ) nitrido complex induced by visible light.

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Veröffentlicht in:Chemical science (Cambridge) 2021-11, Vol.12 (43), p.14494-14498
Hauptverfasser: Xiang, Jing, Peng, Min, Pan, Yi, Luo, Li-Juan, Cheng, Shun-Cheung, Jin, Xin-Xin, Yiu, Shek-Man, Man, Wai-Lun, Ko, Chi-Chiu, Lau, Kai-Chung, Lau, Tai-Chu
Format: Artikel
Sprache:eng
Schlagworte:
Alkylamines
Amines
Chemistry
Dealkylation
Osmium
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Zusammenfassung:N -Dealkylation of amines by metal oxo intermediates (MO) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N -dealkylation of various alkylamines by a luminescent osmium( vi ) nitrido complex induced by visible light.
ISSN:2041-6520
2041-6539
DOI:10.1039/d1sc04369b