Achieving stable Na metal cycling via polydopamine/multilayer graphene coating of a polypropylene separator
Sodium metal batteries are considered one of the most promising low-cost high-energy-density electrochemical energy storage systems. However, the growth of unfavourable Na metal deposition and the limited cell cycle life hamper the application of this battery system at a large scale. Here, we propos...
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Veröffentlicht in: | Nature communications 2021-10, Vol.12 (1), p.5786-5786, Article 5786 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Sodium metal batteries are considered one of the most promising low-cost high-energy-density electrochemical energy storage systems. However, the growth of unfavourable Na metal deposition and the limited cell cycle life hamper the application of this battery system at a large scale. Here, we propose the use of polypropylene separator coated with a composite material comprising polydopamine and multilayer graphene to tackle these issues. The oxygen- and nitrogen- containing moieties as well as the nano- and meso- porous network of the coating allow cycling of Na metal electrodes in symmetric cell configuration for over 2000 h with a stable 4 mV overpotential at 1 mA cm
−2
. When tested in full Na || Na
3
V
2
(PO
4
)
3
coin cell, the coated separator enables the delivery of a stable capacity of about 100 mAh g
−1
for 500 cycles (90% capacity retention) at a specific current of 235 mA g
−1
and satisfactory rate capability performances (i.e., 75 mAh g
−1
at 3.5 A g
−1
).
The development of future Na metal batteries relies on the cycling stability of the metallic anode. Here, the authors propose a polypropylene separator functionalized with polydopamine and multilayer graphene to enable stable and prolonged Na metal cell cycling. |
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ISSN: | 2041-1723 2041-1723 |
DOI: | 10.1038/s41467-021-26032-1 |