Selective C–H Iodination of (Hetero)arenes

Iodoarenes are versatile intermediates and common synthetic targets in organic synthesis. Here, we present a strategy for selective C–H iodination of (hetero)­arenes with a broad functional group tolerance. We demonstrate the utility and differentiation to other iodination methods of supposed sulfon...

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Veröffentlicht in:Organic letters 2021-07, Vol.23 (13), p.5024-5027
Hauptverfasser: Tanwar, Lalita, Börgel, Jonas, Lehmann, Johannes, Ritter, Tobias
Format: Artikel
Sprache:eng
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Zusammenfassung:Iodoarenes are versatile intermediates and common synthetic targets in organic synthesis. Here, we present a strategy for selective C–H iodination of (hetero)­arenes with a broad functional group tolerance. We demonstrate the utility and differentiation to other iodination methods of supposed sulfonyl hypoiodites for a set of carboarenes and heteroarenes.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.1c01530