Graphene‐Like Carbon Film Wrapped Tin (II) Sulfide Nanosheet Arrays on Porous Carbon Fibers with Enhanced Electrochemical Kinetics as High‐Performance Li and Na Ion Battery Anodes

SnS, is a promising anode material for lithium ion batteries (LIBs) and sodium ion batteries (SIBs), however, undergoes poor cyclic lifespan due to its huge volume changes and bad electroconductivity. Here, a modified CVD method is used to directly grow graphene‐like carbon film on the surface of Sn...

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Veröffentlicht in:Advanced science 2020-09, Vol.7 (18), p.1903045-n/a, Article 1903045
Hauptverfasser: Cui, Zhe, He, Shu‐Ang, Liu, Qian, Guan, Guoqiang, Zhang, Wenlong, Xu, Chaoting, Zhu, Jinqi, Feng, Ping, Hu, Junqing, Zou, Rujia, Zhu, Meifang
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Sprache:eng
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Zusammenfassung:SnS, is a promising anode material for lithium ion batteries (LIBs) and sodium ion batteries (SIBs), however, undergoes poor cyclic lifespan due to its huge volume changes and bad electroconductivity. Here, a modified CVD method is used to directly grow graphene‐like carbon film on the surface of SnS nanosheet arrays which are supported by Co‐, N‐modified porous carbon fibers (CCF@SnS@G). In the strategy, the SnS nanosheet arrays confined into the integrated carbon matrix containing porous carbon fibers and graphene‐like carbon film, perform a greatly improved electrochemical performance. In situ TEM experiments reveal that the vertical graphene‐like carbon film can not only protect the SnS nanosheet from destruction well and enhance the conductivity, but also transforms SnS nanosheet into ultrafine nanoparticles to promote the electrochemical kinetics. Systematic electrochemical investigations exhibit that the CCF@SnS@G electrode delivers a stable reversible capacity of 529 mAh g−1 at a high current density of 5 A g−1 for LIBs and 541.4 mAh g−1 at 2 A g−1 for SIBs, suggesting its good potential for anode electrodes. SnS nanosheet arrays sandwiched into the integrated carbon matrix containing porous carbon fibers and graphene‐like carbon film are prepared and provide a great improvement in the electrochemical performance of lithium ion and sodium ion batteries.
ISSN:2198-3844
2198-3844
DOI:10.1002/advs.201903045