Electrophotocatalytic SNAr Reactions of Unactivated Aryl Fluorides at Ambient Temperature and Without Base

Electrophotocatalytic SNAr Reactions of Unactivated Aryl Fluorides at Ambient Temperature and Without Base

The electrophotocatalytic SNAr reaction of unactivated aryl fluorides at ambient temperature without strong base is demonstrated. Unactivated aryl fluorides engage in SNAr reactions at room temperature and without a strong base using DDQ as an electrophotocatalyst.

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Veröffentlicht in:Angewandte Chemie International Edition 2020-01, Vol.59 (2), p.658-662
Hauptverfasser: Huang, He, Lambert, Tristan H.
Format: Artikel
Sprache:eng
Schlagworte:
Ambient temperature
Aromatic compounds
arylation
electrochemistry
electrophotocatalysis
Fluorides
photochemistry
SNAr
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Zusammenfassung:The electrophotocatalytic SNAr reaction of unactivated aryl fluorides at ambient temperature without strong base is demonstrated. Unactivated aryl fluorides engage in SNAr reactions at room temperature and without a strong base using DDQ as an electrophotocatalyst.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201909983