H2O2 photoproduction inside H2O and H2O:O2 ices at 20–140 K

We report the results of laboratory measurements of H 2 O 2 production inside thin (50 nm thickness) H 2 O and H 2 O:O 2 ice samples irradiated by 121.6 nm photons at different temperatures. In the case of H 2 O ice, H 2 O 2 is formed at the temperatures below 60 К. In the case of H 2 O:O 2 ice, H 2...

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Veröffentlicht in:Scientific reports 2019-08, Vol.9 (1), p.1-9, Article 11375
Hauptverfasser: Kulikov, Mikhail Yu, Feigin, Alexander M., Schrems, Otto
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Sprache:eng
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Zusammenfassung:We report the results of laboratory measurements of H 2 O 2 production inside thin (50 nm thickness) H 2 O and H 2 O:O 2 ice samples irradiated by 121.6 nm photons at different temperatures. In the case of H 2 O ice, H 2 O 2 is formed at the temperatures below 60 К. In the case of H 2 O:O 2 ice, H 2 O 2 is formed in the 20–140 К range. For H 2 O:O 2  = 9:1 ice, we derived H 2 O 2 photochemical quantum yield as a function of sample irradiation temperature. The obtained data can be used for evaluation of H 2 O 2 photoproduction at the surface of astrophysical water ice bodies and inside the particles of Noctilucent Clouds in the Earth’s atmosphere.
ISSN:2045-2322
2045-2322
DOI:10.1038/s41598-019-47915-w