Inter-molecular hydrogen bonding in isostructural pincer complexes [OH-( t -Bu POCOP t -Bu ) M Cl] ( M = Pd and Pt)

In the crystal structure of the isostructural title compounds, namely {2,6-bis-[(di- -butyl-phosphan-yl)-oxy]-4-hy-droxy-phen-yl}chlorido-palladium(II), [Pd(C H O P )Cl], , and {2,6-bis-[(di- -butyl-phosphan-yl)-oxy]-4-hy-droxy-phen-yl}chlorido-platinum(II), [Pt(C H O P )Cl], , the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an inter-action of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand.