Effect of Potassium Ions on the Formation of Mixed-Valence Manganese Oxide/Graphene Nanocomposites

One-pot synthesis of mixed-valence manganese oxide (MnO )/potassium ion-doped reduced graphene oxide (rGO) composites for efficient electrochemical supercapacitors is introduced. Using manganese nitrate and potassium permanganate as co-precursors for the MnO and by directly annealing the rGO without tedious purification steps, as described herein, MnO /rGO composites with a high specific capacitance of 1955.6 F g at a current density of 1 A g are achieved. It is found that the presence of potassium ions helps in the development of mixed-valence MnO on the surface of the rGO.