Crystal structure of 1-hepta-fluoro-tolyl- closo -1,2-dicarbadodeca-borane

Crystal structure of 1-hepta-fluoro-tolyl- closo -1,2-dicarbadodeca-borane

The mol-ecular structure of the title compound 1-(2',3',5',6'-tetra-fluoro-4'-trifluoro-methyl-phen-yl)- -1,2-dicarbadodeca-borane, C H B F , features an intra-molecular -F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta-fluoro-tolyl subst...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2019-04, Vol.75 (Pt 4), p.512-515
Hauptverfasser: Watson, James D, Benton, Amanda, Tricas, Hugo, Rosair, Georgina M, Welch, Alan J
Format: Artikel
Sprache:eng
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Research Communications
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Zusammenfassung:The mol-ecular structure of the title compound 1-(2',3',5',6'-tetra-fluoro-4'-trifluoro-methyl-phen-yl)- -1,2-dicarbadodeca-borane, C H B F , features an intra-molecular -F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta-fluoro-tolyl substituent in which the plane of the aryl ring nearly eclipses the C1-C2 cage connectivity.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989019004067