Embedding Carbon Dots in Superabsorbent Polymers for Additive Manufacturing
A type of orange carbon dots (O-CDs) synthesized via an ultrasonication route with citric acid and 1,2-phenylenediamine as precursors was embedded into sodium polyacrylate (SPA) as the ink for 3D printing. Characterizations of these spherical O-CDs revealed an ultra-small size (~2 nm) and excitation...
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| Veröffentlicht in: | Polymers 2018-08, Vol.10 (8), p.921 |
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| creator | Zhou, Yiqun Mintz, Keenan J Oztan, Cagri Y Hettiarachchi, Sajini D Peng, Zhili Seven, Elif S Liyanage, Piumi Y De La Torre, Sabrina Celik, Emrah Leblanc, Roger M |
| description | A type of orange carbon dots (O-CDs) synthesized via an ultrasonication route with citric acid and 1,2-phenylenediamine as precursors was embedded into sodium polyacrylate (SPA) as the ink for 3D printing. Characterizations of these spherical O-CDs revealed an ultra-small size (~2 nm) and excitation-independent, but solvent dependent, emission. The O-CDs were evenly distributed with low degree of aggregation in sodium polyacrylate (SPA), which was achieved due to the property that SPA can absorb water together with O-CDs. The 3D printed photoluminescent objective with the ink revealed a great potential for high yield application of these materials for additive manufacturing. This also represents the first time, bare CDs have been reported as a photoluminescent material in 3D printing, as well as the first time SPA has been reported as a material for 3D printing. |
| doi_str_mv | 10.3390/polym10080921 |
| format | Article |
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Characterizations of these spherical O-CDs revealed an ultra-small size (~2 nm) and excitation-independent, but solvent dependent, emission. The O-CDs were evenly distributed with low degree of aggregation in sodium polyacrylate (SPA), which was achieved due to the property that SPA can absorb water together with O-CDs. The 3D printed photoluminescent objective with the ink revealed a great potential for high yield application of these materials for additive manufacturing. This also represents the first time, bare CDs have been reported as a photoluminescent material in 3D printing, as well as the first time SPA has been reported as a material for 3D printing.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym10080921</identifier><identifier>PMID: 30960846</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>3-D printers ; Additive manufacturing ; Aqueous solutions ; Carbon ; Carbon dots ; Citric acid ; Communication ; Composite materials ; Embedding ; Fourier transforms ; Nanocomposites ; Nanomaterials ; Phenylenediamine ; Photoluminescence ; Polymers ; Quantum dots ; Superabsorbent polymers ; Three dimensional printing</subject><ispartof>Polymers, 2018-08, Vol.10 (8), p.921</ispartof><rights>2018. This work is licensed under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2018 by the authors. 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c481t-b5ab7e06b87b696671ff5c6158766acf398c3de87976eed6332b756517eebd353</citedby><cites>FETCH-LOGICAL-c481t-b5ab7e06b87b696671ff5c6158766acf398c3de87976eed6332b756517eebd353</cites><orcidid>0000-0001-9688-7504</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6403561/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6403561/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30960846$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhou, Yiqun</creatorcontrib><creatorcontrib>Mintz, Keenan J</creatorcontrib><creatorcontrib>Oztan, Cagri Y</creatorcontrib><creatorcontrib>Hettiarachchi, Sajini D</creatorcontrib><creatorcontrib>Peng, Zhili</creatorcontrib><creatorcontrib>Seven, Elif S</creatorcontrib><creatorcontrib>Liyanage, Piumi Y</creatorcontrib><creatorcontrib>De La Torre, Sabrina</creatorcontrib><creatorcontrib>Celik, Emrah</creatorcontrib><creatorcontrib>Leblanc, Roger M</creatorcontrib><title>Embedding Carbon Dots in Superabsorbent Polymers for Additive Manufacturing</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>A type of orange carbon dots (O-CDs) synthesized via an ultrasonication route with citric acid and 1,2-phenylenediamine as precursors was embedded into sodium polyacrylate (SPA) as the ink for 3D printing. Characterizations of these spherical O-CDs revealed an ultra-small size (~2 nm) and excitation-independent, but solvent dependent, emission. The O-CDs were evenly distributed with low degree of aggregation in sodium polyacrylate (SPA), which was achieved due to the property that SPA can absorb water together with O-CDs. The 3D printed photoluminescent objective with the ink revealed a great potential for high yield application of these materials for additive manufacturing. This also represents the first time, bare CDs have been reported as a photoluminescent material in 3D printing, as well as the first time SPA has been reported as a material for 3D printing.</description><subject>3-D printers</subject><subject>Additive manufacturing</subject><subject>Aqueous solutions</subject><subject>Carbon</subject><subject>Carbon dots</subject><subject>Citric acid</subject><subject>Communication</subject><subject>Composite materials</subject><subject>Embedding</subject><subject>Fourier transforms</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Phenylenediamine</subject><subject>Photoluminescence</subject><subject>Polymers</subject><subject>Quantum dots</subject><subject>Superabsorbent polymers</subject><subject>Three dimensional printing</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkc1LxDAQxYMorugevUrBi5dqPtpJexFkXT9wRUE9h6SdrpU2WZNW2P_eLrsu6lwykF_evMkj5JjRcyFyerFwzbJllGY052yHHHAqRZwIoLu_-hEZh_BBh0pSACb3yUjQHGiWwAF5mLYGy7K282iivXE2unZdiGobvfQL9NoE5w3aLnpejUIfosr56Gp40dVfGD1q21e66Ho_KByRvUo3Aceb85C83UxfJ3fx7On2fnI1i4skY11sUm0kUjCZNJADSFZVaQEszSSALiqRZ4UoMZO5BMQShOBGppAyiWhKkYpDcrnWXfSmxbIY7HndqIWvW-2Xyula_b2x9buauy8FCRUpsEHgbCPg3WePoVNtHQpsGm3R9UFxToFzIeQKPf2Hfrje22E9xRmH4T8pX1Hxmiq8C8FjtTXDqFolpf4kNfAnvzfY0j-5iG_ZH4-p</recordid><startdate>20180817</startdate><enddate>20180817</enddate><creator>Zhou, Yiqun</creator><creator>Mintz, Keenan J</creator><creator>Oztan, Cagri Y</creator><creator>Hettiarachchi, Sajini D</creator><creator>Peng, Zhili</creator><creator>Seven, Elif S</creator><creator>Liyanage, Piumi Y</creator><creator>De La Torre, Sabrina</creator><creator>Celik, Emrah</creator><creator>Leblanc, Roger M</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-9688-7504</orcidid></search><sort><creationdate>20180817</creationdate><title>Embedding Carbon Dots in Superabsorbent Polymers for Additive Manufacturing</title><author>Zhou, Yiqun ; Mintz, Keenan J ; Oztan, Cagri Y ; Hettiarachchi, Sajini D ; Peng, Zhili ; Seven, Elif S ; Liyanage, Piumi Y ; De La Torre, Sabrina ; Celik, Emrah ; Leblanc, Roger M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c481t-b5ab7e06b87b696671ff5c6158766acf398c3de87976eed6332b756517eebd353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>3-D printers</topic><topic>Additive manufacturing</topic><topic>Aqueous solutions</topic><topic>Carbon</topic><topic>Carbon dots</topic><topic>Citric acid</topic><topic>Communication</topic><topic>Composite materials</topic><topic>Embedding</topic><topic>Fourier transforms</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Phenylenediamine</topic><topic>Photoluminescence</topic><topic>Polymers</topic><topic>Quantum dots</topic><topic>Superabsorbent polymers</topic><topic>Three dimensional printing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Yiqun</creatorcontrib><creatorcontrib>Mintz, Keenan J</creatorcontrib><creatorcontrib>Oztan, Cagri Y</creatorcontrib><creatorcontrib>Hettiarachchi, Sajini D</creatorcontrib><creatorcontrib>Peng, Zhili</creatorcontrib><creatorcontrib>Seven, Elif S</creatorcontrib><creatorcontrib>Liyanage, Piumi Y</creatorcontrib><creatorcontrib>De La Torre, Sabrina</creatorcontrib><creatorcontrib>Celik, Emrah</creatorcontrib><creatorcontrib>Leblanc, Roger M</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Yiqun</au><au>Mintz, Keenan J</au><au>Oztan, Cagri Y</au><au>Hettiarachchi, Sajini D</au><au>Peng, Zhili</au><au>Seven, Elif S</au><au>Liyanage, Piumi Y</au><au>De La Torre, Sabrina</au><au>Celik, Emrah</au><au>Leblanc, Roger M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Embedding Carbon Dots in Superabsorbent Polymers for Additive Manufacturing</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2018-08-17</date><risdate>2018</risdate><volume>10</volume><issue>8</issue><spage>921</spage><pages>921-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>A type of orange carbon dots (O-CDs) synthesized via an ultrasonication route with citric acid and 1,2-phenylenediamine as precursors was embedded into sodium polyacrylate (SPA) as the ink for 3D printing. 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| subjects | 3-D printers Additive manufacturing Aqueous solutions Carbon Carbon dots Citric acid Communication Composite materials Embedding Fourier transforms Nanocomposites Nanomaterials Phenylenediamine Photoluminescence Polymers Quantum dots Superabsorbent polymers Three dimensional printing |
| title | Embedding Carbon Dots in Superabsorbent Polymers for Additive Manufacturing |
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