Bench-Stable Nickel Precatalysts with Heck-type Activation

Bench-Stable Nickel Precatalysts with Heck-type Activation

Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel­(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction.

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Veröffentlicht in:Organometallics 2018-08, Vol.37 (16), p.2716-2722
Hauptverfasser: Weber, Jessica M, Longstreet, Ashley R, Jamison, Timothy F
Format: Artikel
Sprache:eng
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Zusammenfassung:Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel­(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.8b00351