Crystal structure of bis-(diiso-propyl-ammonium) cis -di-iodido-bis-(oxolato-κ 2 O 1 , O 2 )stannate(IV)

In the title compound, ( Pr NH ) [SnI (C O ) ], which was prepared by reacting ( Pr NH ) ·C O with SnI in a 2:1 molar ratio in a mixed ethanol-aceto-nitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a configuration. In the crystal, the...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2018-04, Vol.74 (Pt 4), p.502-504
Hauptverfasser: Sarr, Bougar, Diop, Cheikh Abdoul Khadir, Sidibé, Mamadou, Rousselin, Yoann
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Sprache:eng
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Zusammenfassung:In the title compound, ( Pr NH ) [SnI (C O ) ], which was prepared by reacting ( Pr NH ) ·C O with SnI in a 2:1 molar ratio in a mixed ethanol-aceto-nitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a configuration. In the crystal, the cations are linked to the anions by N-H⋯O and bifurcated N-H⋯(O,O) hydrogen bonds, generating [10-1] chains.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989018003602