Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane

Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane

Abstract A simple, one-pot, and high-yielding synthesis of 1,3-diphenyldisiloxane is presented. The preparation of similar symmetrical disiloxane materials is also accomplished with this same protocol. This mechano-chemical procedure is efficient and highly scalable, furnishing a convenient route to...

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Veröffentlicht in:Synthesis (Stuttgart) 2018-01, Vol.50 (2), p.278-281
Hauptverfasser: Buonomo, Joseph A., Eiden, Carter G., Aldrich, Courtney C.
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract A simple, one-pot, and high-yielding synthesis of 1,3-diphenyldisiloxane is presented. The preparation of similar symmetrical disiloxane materials is also accomplished with this same protocol. This mechano-chemical procedure is efficient and highly scalable, furnishing a convenient route to hydrido-disiloxanes from widely accessible commercially available silanes.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0036-1588580