Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes

A Ni-catalyzed method for arylboration is disclosed. The method allows for highly stereoselective arylboration of unactivated alkenes. The reactions utilize a simple Ni-catalyst and work with a broad range of alkenes and aryl bromides. The products represent useful intermediates for chemical synthes...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-01, Vol.140 (1), p.159-162
Hauptverfasser:	Logan, Kaitlyn M, Sardini, Stephen R, White, Sean D, Brown, M. Kevin
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Boron Compounds - chemical synthesis Boron Compounds - chemistry Catalysis Molecular Structure Nickel - chemistry Stereoisomerism
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A Ni-catalyzed method for arylboration is disclosed. The method allows for highly stereoselective arylboration of unactivated alkenes. The reactions utilize a simple Ni-catalyst and work with a broad range of alkenes and aryl bromides. The products represent useful intermediates for chemical synthesis due to the versatility of the C–B bond. Preliminary mechanistic details of the method are also disclosed.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/jacs.7b12160