Redox-promoted associative assembly of metal-organic materials

Redox-promoted associative assembly of metal-organic materials

We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of -quinones, which we introduce as versatile oxidants for mechan...

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Veröffentlicht in:Chemical science (Cambridge) 2016-01, Vol.7 (1), p.707-712
Hauptverfasser: Glavinović, Martin, Qi, Feng, Katsenis, Athanassios D, Friščić, Tomislav, Lumb, Jean-Philip
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Associative
Chemistry
Hinges
Mechanochemistry
Self assembly
Strategy
Synthesis
Transformations
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Beschreibung
Zusammenfassung:We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of -quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal-organic materials from elementary metals.
ISSN:2041-6520
2041-6539
DOI:10.1039/c5sc02214b