Crystal structure of 3-amino-pyridinium 1'-carb-oxy-ferrocene-1-carboxyl-ate
The structure of the title salt, (C H N )[Fe(C H O )(C H O )], consists of 3-amino-pyridinium cations and 1'-carb-oxy-ferrocene-1-carboxyl-ate monoanions. The ferrocenyl moiety of the anion adopts a typical sandwich structure, with Fe-C distances in the range 2.0270 (15)-2.0568 (17) Å. The anio...
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| Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2017-06, Vol.73 (Pt 6), p.856-858 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The structure of the title salt, (C
H
N
)[Fe(C
H
O
)(C
H
O
)], consists of 3-amino-pyridinium cations and 1'-carb-oxy-ferrocene-1-carboxyl-ate monoanions. The ferrocenyl moiety of the anion adopts a typical sandwich structure, with Fe-C distances in the range 2.0270 (15)-2.0568 (17) Å. The anion possesses an eclipsed conformation, with the torsion angle φ (C
-Cp
-Cp
- C
) equal to 66.0°. The conformations of other 1'-carb-oxy-ferrocene-1-carboxyl-ate monoanions are compared and analyzed on the basis of literature data. |
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| ISSN: | 2056-9890 2056-9890 |
| DOI: | 10.1107/S2056989017007058 |