Expansion of the ADOR Strategy for the Synthesis of Zeolites: The Synthesis of IPC‐12 from Zeolite UOV

The assembly–disassembly–organization–reassembly (ADOR) process has been used to disassemble a parent zeolite with the UOV structure type and then reassemble the resulting layers into a novel structure, IPC‐12. The structure of the material has previously been predicted computationally and confirmed...

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Veröffentlicht in:Angewandte Chemie International Edition 2017-04, Vol.56 (15), p.4324-4327
Hauptverfasser: Kasneryk, Valeryia, Shamzhy, Mariya, Opanasenko, Maksym, Wheatley, Paul S., Morris, Samuel A., Russell, Samantha E., Mayoral, Alvaro, Trachta, Michal, Čejka, Jiří, Morris, Russell E.
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Sprache:eng
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Zusammenfassung:The assembly–disassembly–organization–reassembly (ADOR) process has been used to disassemble a parent zeolite with the UOV structure type and then reassemble the resulting layers into a novel structure, IPC‐12. The structure of the material has previously been predicted computationally and confirmed in our experiments using X‐ray diffraction and atomic resolution STEM‐HAADF electron microscopy. This is the first successful application of the ADOR process to a material with porous layers. A germane assembly: The synthesis of a new zeolite IPC‐12 using the assembly–disassembly–organization–reassembly (ADOR) transformation of a germanosilicate zeolite with the UOV topology is reported.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201700590