Synthesis and applications of rhodacyclopentanones derived from C-C bond activation

Synthesis and applications of rhodacyclopentanones derived from C-C bond activation

Rhodacyclopentanones, an "sp(3)-rich" class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C-C bond activation of cyclobutan...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (72), p.10817-10829
Hauptverfasser: Shaw, Megan H, Bower, John F
Format: Artikel
Sprache:eng
Schlagworte:
Activation
Bonding
Carbon-carbon composites
Catalysis
chemical bonding
chemical compounds
chemical reactions
Metalorganic compounds
Organic compounds
Strategy
Synthesis
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Zusammenfassung:Rhodacyclopentanones, an "sp(3)-rich" class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C-C bond activation of cyclobutanones or cyclopropanes. The scope and mechanism of methodologies that exploit these activation modes is outlined.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c6cc04359c