Transparent Films from CO2-Based Polyunsaturated Poly(ether carbonate)s: A Novel Synthesis Strategy and Fast Curing

Transparent films were prepared by cross‐linking polyunsaturated poly(ether carbonate)s obtained by the multicomponent polymerization of CO2, propylene oxide, maleic anhydride, and allyl glycidyl ether. Poly(ether carbonate)s with ABXBA multiblock structures were obtained by sequential addition of mixtures of propylene oxide/maleic anhydride and propylene oxide/allyl glycidyl ether during the polymerization. The simultaneous addition of both monomer mixtures provided poly(ether carbonate)s with AXA triblock structures. Both types of polyunsaturated poly(ether carbonate)s are characterized by diverse functional groups, that is, terminal hydroxy groups, maleate moieties along the polymer backbone, and pendant allyl groups that allow for versatile polymer chemistry. The combination of double bonds substituted with electron‐acceptor and electron‐donor groups enables particularly facile UV‐ or redox‐initiated free‐radical curing. The resulting materials are transparent and highly interesting for coating applications. Well connected: Transparent films were obtained by cross‐linking polyunsaturated poly(ether carbonate)s, which were obtained by the one‐pot multicomponent polymerization of CO2, epoxide, maleic anhydride, and allyl glycidyl ether. The presence of double bonds substituted with electron‐acceptor and electron‐donor groups accelerates the curing step and enables the facile preparation of coatings by UV‐initiated free‐radical curing.