Production and characterization of absorbent heat from the bark of residual Brazil nut bark (Bertholletia Excelsa l.)

Background The increasing efforts to reduce the environmental impact on the Amazon’s natural resources are focusing on watercourses that pass through effluents with high concentrations of heavy metals. The adsorption by absorbent is one of the methods used to remove metallic ions. In this assignment...

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Veröffentlicht in:BMC chemistry 2015-06, Vol.9 (1), p.36-36, Article 36
Hauptverfasser: Melo, Selma dos Santos, Diniz, Joel Estevão de Melo, Guimarães, Jonilson Heslei, Costa, Josivan da Silva, Brasil, Davi do Socorro Barros, de Morais, Sílvia Simone dos Santos, Brito, Daímio Chaves, Carvalho, José Carlos Tavares, dos Santos, Cleydson Breno Rodrigues, da Silva, Denilson Luz
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Sprache:eng
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Zusammenfassung:Background The increasing efforts to reduce the environmental impact on the Amazon’s natural resources are focusing on watercourses that pass through effluents with high concentrations of heavy metals. The adsorption by absorbent is one of the methods used to remove metallic ions. In this assignment, the preparation of activated carbon from Brazil nut bark (Bertholletia excelsa l.) , which is a waste material produced from the use of seeds in foodstuffs and cosmetics, is shown. Results The absorbent was carbonized at 400 °C in 3 h and activated at 800 °C in 2 h, having received the name of AC2, and, the specific area, pore size, real and apparent densities, porosity, scanning electron microscopy (SEM) coupled to energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), pH, moisture, fixed carbon and surface functional groups by Boehm method and Fourier transformed infrared spectroscopy (FTIR) were characterized. According to the results, the carbon presented alkaline characteristic, mesoporosity, average pore diameters of 2.203 nm and specific surface area by BET of 464.835 m 2  g -1 . The efficiency of removal was performed in synthetic solutions of copper sulphate (II) pentahydrate (CuSO 4. 5H 2 O), evaluating the influence of pH, initial concentration of copper solution (II), particle diameter and time contact of the adsorbent in solution. The results of higher removal percentages were to pH 5.09, initial concentration of 50, 100 and 150 mg -1 diameter 0.595 
ISSN:1752-153X
1752-153X
2661-801X
DOI:10.1186/s13065-015-0114-3