3S-fluoroproline as a probe to monitor proline isomerization during proein folding by 19F-NMR

3S-fluoroproline as a probe to monitor proline isomerization during proein folding by 19F-NMR

Variable-temperature inversion transfer NMR is used to determine the kinetic and thermodynamic parameters of cis-trans isomerization of N-Ac-(3 R ) and (3 S )-fluoroproline-OMe.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-05 (23), p.3366-3368
Hauptverfasser: Thomas, Colin A., Talaty, Erach R., Bann, James G.
Format: Artikel
Sprache:eng
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Zusammenfassung:Variable-temperature inversion transfer NMR is used to determine the kinetic and thermodynamic parameters of cis-trans isomerization of N-Ac-(3 R ) and (3 S )-fluoroproline-OMe.
ISSN:1359-7345
1364-548X
DOI:10.1039/b821952d