Inelastic Electron Tunneling Spectroscopy of Nucleic Acid Derivatives

Inelastic electron tunneling spectra of nucleosides and nucleotides are presented which show that detailed information on the vibrational spectra of these molecules can be obtained from a few micrograms of material. A series of studies on adenine derivatives demonstrates that unambiguous identificat...

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Veröffentlicht in:	Proc. Natl. Acad. Sci. U.S.A.; (United States) 1976-05, Vol.73 (5), p.1598-1602
Hauptverfasser:	Clark, James M., Coleman, R. V.
Format:	Artikel
Sprache:	eng
Schlagworte:	400104 - Spectral Procedures- (-1987) 550200 - Biochemistry Adenine Nucleotides ADENINES AMINES BASIC BIOLOGICAL SCIENCES CHEMICAL ANALYSIS Chemical bases Cytosine Nucleotides ELECTRON SPECTROSCOPY Electron tunneling HETEROCYCLIC COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Molecular Conformation Molecular spectra Molecules Nucleic acids NUCLEOSIDES NUCLEOTIDES ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS Phosphates PURINES Raman scattering RIBOSIDES SPECTROSCOPY Spectrum Analysis - methods Structure-Activity Relationship Vibration Vibrational spectra
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Beschreibung
Zusammenfassung:	Inelastic electron tunneling spectra of nucleosides and nucleotides are presented which show that detailed information on the vibrational spectra of these molecules can be obtained from a few micrograms of material. A series of studies on adenine derivatives demonstrates that unambiguous identification of a large number of slightly different derivatives can be carried out by means of this technique.
ISSN:	0027-8424 1091-6490
DOI:	10.1073/pnas.73.5.1598