Crystal structure of poly[μ-acetato-bis-[μ-2-oxo-2-(quinolin-8-yl)ethano-ato]tris-odium]

The title compound [Na3(C11H6NO3)2(C2H3O2)] n , crystallized through diffusion of diethyl ether into methanol as needles. There are three crystallographically independent Na(+) cations present, each exhib-it-ing a distorted octa-hedral coordination geometry, two through coordination by five O atoms...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2014-11, Vol.70 (Pt 11), p.m385-m386
Hauptverfasser: Nicholls, Rachel L, Pask, Christopher M, Nguyen, Bao
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound [Na3(C11H6NO3)2(C2H3O2)] n , crystallized through diffusion of diethyl ether into methanol as needles. There are three crystallographically independent Na(+) cations present, each exhib-it-ing a distorted octa-hedral coordination geometry, two through coordination by five O atoms and one N atom, and one through coordination by six O atoms. A series of inter-molecular O⋯Na and N⋯Na contacts leads to the formation of chains along the a-axis direction.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536814023423