Suzuki–Miyaura Cross-Coupling of Brominated 2,1-Borazaronaphthalenes with Potassium Alkenyltrifluoroborates

Suzuki–Miyaura Cross-Coupling of Brominated 2,1-Borazaronaphthalenes with Potassium Alkenyltrifluoroborates

Conditions have been developed for the palladium-catalyzed cross-coupling of 3-bromo-2,1-borazaronaphthalenes with potassium alkenyltrifluoroborates. Twenty-seven alkenyl-substituted azaborines have been synthesized through this method, providing access to a family of 2,1-borazaronaphthalenes with a...

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Veröffentlicht in:Journal of organic chemistry 2014-11, Vol.79 (22), p.11199-11204
Hauptverfasser: Molander, Gary A, Wisniewski, Steven R, Etemadi-Davan, Elham
Format: Artikel
Sprache:eng
Schlagworte:
Borates - chemistry
Catalysis
Halogenation
Hydrocarbons, Fluorinated - chemistry
Molecular Structure
Palladium - chemistry
Potassium - chemistry
Stereoisomerism
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Zusammenfassung:Conditions have been developed for the palladium-catalyzed cross-coupling of 3-bromo-2,1-borazaronaphthalenes with potassium alkenyltrifluoroborates. Twenty-seven alkenyl-substituted azaborines have been synthesized through this method, providing access to a family of 2,1-borazaronaphthalenes with alkenyl substitution at the C3 position.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo502260x