Expansion of the Ligand Knowledge Base for Chelating P,P-Donor Ligands (LKB-PP)

Expansion of the Ligand Knowledge Base for Chelating P,P-Donor Ligands (LKB-PP)

We have expanded the ligand knowledge base for bidentate P,P- and P,N-donor ligands (LKB-PP, Organometallics 2008, 27, 1372–1383 ) by 208 ligands and introduced an additional steric descriptor (nHe8). This expanded knowledge base now captures information on 334 bidentate ligands and has been process...

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Veröffentlicht in:Organometallics 2012-08, Vol.31 (15), p.5302-5306
Hauptverfasser: Jover, Jesús, Fey, Natalie, Harvey, Jeremy N, Lloyd-Jones, Guy C, Orpen, A. Guy, Owen-Smith, Gareth J. J, Murray, Paul, Hose, David R. J, Osborne, Robert, Purdie, Mark
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Sprache:eng
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Zusammenfassung:We have expanded the ligand knowledge base for bidentate P,P- and P,N-donor ligands (LKB-PP, Organometallics 2008, 27, 1372–1383 ) by 208 ligands and introduced an additional steric descriptor (nHe8). This expanded knowledge base now captures information on 334 bidentate ligands and has been processed with principal component analysis (PCA) of the descriptors to produce a detailed map of bidentate ligand space, which better captures ligand variation and has been used for the analysis of ligand properties.
ISSN:0276-7333
1520-6041
DOI:10.1021/om300312t