Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2 O,O′)cobaltate(II)
In the title compound, (C 8 H 12 N) 2 [Co(H 2 P 2 O 7 ) 2 (H 2 O) 2 ], the Co 2+ ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO 6 coordination geometry arising from two chelating diphosphate [H 2 P 2 O 7 ] 2− ligands and two trans water molecules. In...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2014-02, Vol.70 (Pt 3), p.m86-m87 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | In the title compound, (C
8
H
12
N)
2
[Co(H
2
P
2
O
7
)
2
(H
2
O)
2
], the Co
2+
ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO
6
coordination geometry arising from two chelating diphosphate [H
2
P
2
O
7
]
2−
ligands and two
trans
water molecules. In the crystal, the components are linked by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and weak aromatic π–π stacking [shortest centroid–centroid separation = 3.778 (2) Å] interactions. (001) layers of alternating organic cations and complex inorganic anions are apparent. |
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| ISSN: | 1600-5368 |
| DOI: | 10.1107/S1600536814002530 |