Isolation and Characterization of Stable Iron(I) Sulfide Complexes
The first examples of iron(I) sulfide complexes are presented, in contrast with the +2 and +3 oxidation states that are well‐known in synthetic and biological systems. Spectroscopic and computational studies show a high‐spin d7 configuration at the metal. Alkali metal cations play a key role in supp...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-08, Vol.51 (33), p.8247-8250 |
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| container_end_page | 8250 |
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| container_issue | 33 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 51 |
| creator | Rodriguez, Meghan M. Stubbert, Bryan D. Scarborough, Christopher C. Brennessel, William W. Bill, Eckhard Holland, Patrick L. |
| description | The first examples of iron(I) sulfide complexes are presented, in contrast with the +2 and +3 oxidation states that are well‐known in synthetic and biological systems. Spectroscopic and computational studies show a high‐spin d7 configuration at the metal. Alkali metal cations play a key role in supporting the unusually low oxidation state. |
| doi_str_mv | 10.1002/anie.201202211 |
| format | Article |
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| source | MEDLINE; Wiley Online Library All Journals |
| subjects | Alkali metals Biological Cations clusters Computation Ferric Compounds - chemical synthesis Ferric Compounds - chemistry Ferric Compounds - isolation & purification high-spin complexes iron Models, Molecular Molecular Conformation Mössbauer spectroscopy Spectroscopic analysis Spectroscopy Sulfides Sulfides - chemical synthesis Sulfides - chemistry Sulfides - isolation & purification Valence |
| title | Isolation and Characterization of Stable Iron(I) Sulfide Complexes |
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