Isolation and Characterization of Stable Iron(I) Sulfide Complexes

The first examples of iron(I) sulfide complexes are presented, in contrast with the +2 and +3 oxidation states that are well‐known in synthetic and biological systems. Spectroscopic and computational studies show a high‐spin d7 configuration at the metal. Alkali metal cations play a key role in supp...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2012-08, Vol.51 (33), p.8247-8250
Hauptverfasser:	Rodriguez, Meghan M., Stubbert, Bryan D., Scarborough, Christopher C., Brennessel, William W., Bill, Eckhard, Holland, Patrick L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkali metals Biological Cations clusters Computation Ferric Compounds - chemical synthesis Ferric Compounds - chemistry Ferric Compounds - isolation & purification high-spin complexes iron Models, Molecular Molecular Conformation Mössbauer spectroscopy Spectroscopic analysis Spectroscopy Sulfides Sulfides - chemical synthesis Sulfides - chemistry Sulfides - isolation & purification Valence
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The first examples of iron(I) sulfide complexes are presented, in contrast with the +2 and +3 oxidation states that are well‐known in synthetic and biological systems. Spectroscopic and computational studies show a high‐spin d7 configuration at the metal. Alkali metal cations play a key role in supporting the unusually low oxidation state.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201202211