(E)-2-[2-(4-Carb-oxy-phen-yl)ethen-yl]-8-hydroxy-quinolin-1-ium chloride ethanol monosolvate

In the title compound, C18H14NO3 (+)·Cl(-)·CH3CH2OH, the dihedral angle formed by the mean planes of the quinolinium and benzene rings is 3.4 (1)°, while the carb-oxy substituent is tilted at an angle of 4.8 (1)° with respect to the benzene ring. There is a short N-H⋯O contact in the cation. In the...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-11, Vol.69 (Pt 12), p.o1773-o1774
Hauptverfasser: Schulze, Mathias M, Seichter, Wilhelm, Weber, Edwin
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In the title compound, C18H14NO3 (+)·Cl(-)·CH3CH2OH, the dihedral angle formed by the mean planes of the quinolinium and benzene rings is 3.4 (1)°, while the carb-oxy substituent is tilted at an angle of 4.8 (1)° with respect to the benzene ring. There is a short N-H⋯O contact in the cation. In the crystal, due to the planar mol-ecular geometry, two-dimensional aggregates are formed parallel to (221) via C-H⋯O, C-H⋯Cl, O-H⋯Cl and N-H⋯Cl hydrogen bonds. Inter-layer association is accomplished by O-Hethanol⋯Cl and O-H⋯Oethanol hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances vary from 3.6477 (12) to 3.8381 (11) Å]. A supra-molecular three-dimensional architecture results from a stacked arrangement of layers comprising the ionic and hydrogen-bonded components.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813030274