trans-Diaquabis(pyridazine-3-carboxylato-κ2 N 2,O)cobalt(II) dihydrate
The title compound, [Co(C 5 H 3 N 2 O 2 ) 2 (H 2 O) 2 ]·2H 2 O, contains a Co II ion on an inversion center, exhibiting an octahedral coordination geometry. The equatorial plane is formed by two trans -related N , O -bidentate pyridazine-3-carboxylate ligands and the axial positions are occupied b...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-06, Vol.69 (Pt 7), p.m420-m421 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | The title compound, [Co(C
5
H
3
N
2
O
2
)
2
(H
2
O)
2
]·2H
2
O, contains a Co
II
ion on an inversion center, exhibiting an octahedral coordination geometry. The equatorial plane is formed by two
trans
-related
N
,
O
-bidentate pyridazine-3-carboxylate ligands and the axial positions are occupied by two water molecules. The Co
II
complex molecules are stacked in a column along the
a-
axis direction by an O—H⋯N hydrogen bond between the non-coordinating pyridazine N atom and the coordinating water molecule. These columns are further connected into a layer parallel to the
ac
plane by additional hydrogen bonds involving the coordinating and non-coordinating water molecules, and the non-coordinating carboxylate O atom. The crystal packing is completed by interlayer weak C—H⋯O interactions. |
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ISSN: | 1600-5368 |
DOI: | 10.1107/S1600536813017340 |