8-{(E)-[(4-Chloro-phen-yl)imino]-meth-yl}-1,1,7,7-tetra-methyl-1,2,3,5,6,7-hexa-hydro-pyrido[3,2,1-ij]quinolin-9-ol

8-{(E)-[(4-Chloro-phen-yl)imino]-meth-yl}-1,1,7,7-tetra-methyl-1,2,3,5,6,7-hexa-hydro-pyrido[3,2,1-ij]quinolin-9-ol

The title Schiff base, C23H27ClN2O adopts the phenol-imine tautomeric form, with an intra-molecular O-H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa-hydro-pyrido-quinoline unit, as well as the two methyl groups bonded to one of these C ato...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-06, Vol.69 (Pt 6), p.o883-o883
Hauptverfasser: Kantar, Esen Nur, Köysal, Yavuz, Akdemir, Nesuhi, Ağar, Ayşen Alaman, Soylu, Mustafa Serkan
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Sprache:eng
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Organic Papers
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Zusammenfassung:The title Schiff base, C23H27ClN2O adopts the phenol-imine tautomeric form, with an intra-molecular O-H⋯N hydrogen bond, which generates an S(6) ring motif. Three C atoms of the heterocyclic moiety of the hexa-hydro-pyrido-quinoline unit, as well as the two methyl groups bonded to one of these C atoms, are disordered over two set of sites, with anoccupancy ratio of 0.740 (4):0.260 (4).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813012579