Aquabis(4-methylbenzenesulfonato-κO)(η5-pentamethylcyclopentadienyl)rhodium(III) monohydrate
The title half-sandwich rhodium(III) complex, [Rh(C 10 H 15 )(C 7 H 7 O 3 S) 2 (H 2 O)]·H 2 O, consists of a π-bonded pentamethylcyclopentadienyl group, two σ-bonded tosylate groups and an aqua ligand. The structure displays both inter- and intramolecular O—H⋯O hydrogen bonding. The intermole...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-04, Vol.69 (Pt 5), p.m259-m260 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The title half-sandwich rhodium(III) complex, [Rh(C
10
H
15
)(C
7
H
7
O
3
S)
2
(H
2
O)]·H
2
O, consists of a π-bonded pentamethylcyclopentadienyl group, two σ-bonded tosylate groups and an aqua ligand. The structure displays both inter- and intramolecular O—H⋯O hydrogen bonding. The intermolecular hydrogen bonding results in an extended helical chain along a 2
1
screw axis parallel to
c
, due to hydrogen bonding from the coordinating water ligand to the lattice water molecule and then to a sulfonate O atom of a different asymmetric unit. |
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| ISSN: | 1600-5368 |
| DOI: | 10.1107/S160053681300860X |