Directed Synthesis of {Mn18Cu6} Heterometallic Complexes

A two‐step method for the directed synthesis of high‐nuclearity MnIII‐MnII‐CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core.

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2013-02, Vol.52 (7), p.1949-1952
Hauptverfasser:	Milway, Victoria A., Tuna, Floriana, Farrell, Andrew R., Sharp, Laura E., Parsons, Simon, Murrie, Mark
Format:	Artikel
Sprache:	eng
Schlagworte:	Communications copper FABRICATION heterometallic complexes magnetic properties manganese Manganese oxides OXIDES polynuclear clusters Synthesis Transition metals
Online-Zugang:	Volltext
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