Directed Synthesis of {Mn18Cu6} Heterometallic Complexes

Directed Synthesis of {Mn18Cu6} Heterometallic Complexes

A two‐step method for the directed synthesis of high‐nuclearity MnIII‐MnII‐CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core.

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Veröffentlicht in:Angewandte Chemie International Edition 2013-02, Vol.52 (7), p.1949-1952
Hauptverfasser: Milway, Victoria A., Tuna, Floriana, Farrell, Andrew R., Sharp, Laura E., Parsons, Simon, Murrie, Mark
Format: Artikel
Sprache:eng
Schlagworte:
Communications
copper
FABRICATION
heterometallic complexes
magnetic properties
manganese
Manganese oxides
OXIDES
polynuclear clusters
Synthesis
Transition metals
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Zusammenfassung:A two‐step method for the directed synthesis of high‐nuclearity MnIII‐MnII‐CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201208781