Regio- and Stereoselective Synthesis of Cyclic Imidates via Electrophilic Cyclization of 2‑(1-Alkynyl)benzamides. A Correction
The electrophilic cyclization of 2-(1-alkynyl)benzamides affords high yields of cyclic imidates, instead of the previously reported isoindolin-1-ones, where cyclization proceeds on the oxygen of the carbonyl group rather than the nitrogen of the amide functionality. X-ray crystallography and spectro...
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Veröffentlicht in: | Journal of organic chemistry 2012-12, Vol.77 (23), p.10938-10944 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | The electrophilic cyclization of 2-(1-alkynyl)benzamides affords high yields of cyclic imidates, instead of the previously reported isoindolin-1-ones, where cyclization proceeds on the oxygen of the carbonyl group rather than the nitrogen of the amide functionality. X-ray crystallography and spectroscopic techniques have been used to characterize the products. A correction is hereby provided in order to rectify the previous misassignment of structure. |
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ISSN: | 0022-3263 1520-6904 |
DOI: | 10.1021/jo301958q |