Photoisomerization of 1,2-Dihydro-1,2-Azaborine: A Matrix Isolation Study

Photoisomerization of 1,2-Dihydro-1,2-Azaborine: A Matrix Isolation Study

Closing the loop: Photoisomerization of 1,2‐dihydro‐1,2‐azaborine in neon, argon, or xenon at 4 K with UV light (253.7 nm) as part of a matrix isolation study led to the Dewar form as the only photoproduct, in agreement with the vibrational spectra computed for possible isomers of 1,2‐dihydro‐1,2‐az...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-10, Vol.51 (43), p.10880-10883
Hauptverfasser: Brough, Sarah A., Lamm, Ashley N., Liu, Shih-Yuan, Bettinger, Holger F.
Format: Artikel
Sprache:eng
Schlagworte:
Argon
benzene
boron
Boron Compounds - chemistry
Computation
density functional calculations
Dewars
heterocycles
Isomerism
Isomers
matrix isolation
Neon
Ultraviolet Rays
Vibrational spectra
Xenon
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Zusammenfassung:Closing the loop: Photoisomerization of 1,2‐dihydro‐1,2‐azaborine in neon, argon, or xenon at 4 K with UV light (253.7 nm) as part of a matrix isolation study led to the Dewar form as the only photoproduct, in agreement with the vibrational spectra computed for possible isomers of 1,2‐dihydro‐1,2‐azaborine.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201203546