Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes

MOFs on the move: A copper‐coordinated [2]pseudorotaxanate which reacts with zinc nitrate to form threefold interpenetrated networks retains most of its solution‐state chemistry, including its ability to undergo electronic switching of some of the copper(I) ions under redox control.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2012-02, Vol.51 (9), p.2160-2163
Hauptverfasser:	Coskun, Ali, Hmadeh, Mohamad, Barin, Gokhan, Gándara, Felipe, Li, Qiaowei, Choi, Eunwoo, Strutt, Nathan L., Cordes, David B., Slawin, Alexandra M. Z., Stoddart, J. Fraser, Sauvage, Jean-Pierre, Yaghi, Omar M.
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis (homogeneous), solar (photovoltaic), bio-inspired, charge transport, mesostructured materials, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly) Coordination Complexes - chemistry Copper - chemistry Electronics interpenetrated networks Interpenetrating networks mechanostereochemistry Metal-organic frameworks Models, Molecular Nitrates Nitrates - chemistry Oxidation-Reduction reticular chemistry Rotaxanes Rotaxanes - chemistry Switching Zinc Zinc Compounds - chemistry
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