Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes

MOFs on the move: A copper‐coordinated [2]pseudorotaxanate which reacts with zinc nitrate to form threefold interpenetrated networks retains most of its solution‐state chemistry, including its ability to undergo electronic switching of some of the copper(I) ions under redox control.

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Veröffentlicht in:Angewandte Chemie International Edition 2012-02, Vol.51 (9), p.2160-2163
Hauptverfasser: Coskun, Ali, Hmadeh, Mohamad, Barin, Gokhan, Gándara, Felipe, Li, Qiaowei, Choi, Eunwoo, Strutt, Nathan L., Cordes, David B., Slawin, Alexandra M. Z., Stoddart, J. Fraser, Sauvage, Jean-Pierre, Yaghi, Omar M.
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Sprache:eng
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Zusammenfassung:MOFs on the move: A copper‐coordinated [2]pseudorotaxanate which reacts with zinc nitrate to form threefold interpenetrated networks retains most of its solution‐state chemistry, including its ability to undergo electronic switching of some of the copper(I) ions under redox control.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201107873