Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ 2 N , N ′)cobalt(II)
In the title compound, [CoBr 2 (C 12 H 12 N 2 )], the Co II atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Intermolecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-11, Vol.68 (11), p.m1363-m1363 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | m1363 |
|---|---|
| container_issue | 11 |
| container_start_page | m1363 |
| container_title | Acta crystallographica. Section E, Structure reports online |
| container_volume | 68 |
| creator | Shirvan, Sadif A. Haydari Dezfuli, Sara Khazali, Fereydoon Aghajeri, Manouchehr Borsalani, Ali |
| description | In the title compound, [CoBr
2
(C
12
H
12
N
2
)], the Co
II
atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Intermolecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the
bc
plane [centroid–centroid distance = 3.725 (3) Å] are present in the crystal structure. |
| doi_str_mv | 10.1107/S1600536812041980 |
| format | Article |
| fullrecord | <record><control><sourceid>pubmedcentral_cross</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3515117</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>pubmedcentral_primary_oai_pubmedcentral_nih_gov_3515117</sourcerecordid><originalsourceid>FETCH-LOGICAL-c343t-ca87d0a70e72fe5e1b793b8dbd1e2481f27ac5ad0a637a4a18b331f0d9e5b4cb3</originalsourceid><addsrcrecordid>eNplkE1OwzAQhS0EoqVwAHZdtlINHtuJ3Q0SKgUqVbAA1pb_Qo2SpnICUnaciSWH4BCchERFCMRiNDPvzXyLh9AxkBMAIk7vICUkYakESjhMJdlB_U7Cnbb7a-6hg6p6IgRSQWEf9SijkjPO-2h-EUwsi-DKUTpJP1_fsAuFr1dNjumEdrsJmyYGF9Yef7wP6fBmOGmrdca2NDqvR4vF-BDtZTqv_NF3H6CHy_n97Bovb68Ws_MltoyzGlsthSNaEC9o5hMPRkyZkc448JRLyKjQNtHtScqE5hqkYQwy4qY-MdwaNkBnW-7m2RTeWb-uo87VJoZCx0aVOqi_zjqs1GP5olgCCYBoAbAF2FhWVfTZzy8Q1WWq_mXKvgC582oP</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ 2 N , N ′)cobalt(II)</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Shirvan, Sadif A. ; Haydari Dezfuli, Sara ; Khazali, Fereydoon ; Aghajeri, Manouchehr ; Borsalani, Ali</creator><creatorcontrib>Shirvan, Sadif A. ; Haydari Dezfuli, Sara ; Khazali, Fereydoon ; Aghajeri, Manouchehr ; Borsalani, Ali</creatorcontrib><description>In the title compound, [CoBr
2
(C
12
H
12
N
2
)], the Co
II
atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Intermolecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the
bc
plane [centroid–centroid distance = 3.725 (3) Å] are present in the crystal structure.</description><identifier>ISSN: 1600-5368</identifier><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536812041980</identifier><identifier>PMID: 23284344</identifier><language>eng</language><publisher>International Union of Crystallography</publisher><subject>Metal-Organic Papers</subject><ispartof>Acta crystallographica. Section E, Structure reports online, 2012-11, Vol.68 (11), p.m1363-m1363</ispartof><rights>Shirvan et al. 2012 2012</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c343t-ca87d0a70e72fe5e1b793b8dbd1e2481f27ac5ad0a637a4a18b331f0d9e5b4cb3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515117/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515117/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids></links><search><creatorcontrib>Shirvan, Sadif A.</creatorcontrib><creatorcontrib>Haydari Dezfuli, Sara</creatorcontrib><creatorcontrib>Khazali, Fereydoon</creatorcontrib><creatorcontrib>Aghajeri, Manouchehr</creatorcontrib><creatorcontrib>Borsalani, Ali</creatorcontrib><title>Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ 2 N , N ′)cobalt(II)</title><title>Acta crystallographica. Section E, Structure reports online</title><description>In the title compound, [CoBr
2
(C
12
H
12
N
2
)], the Co
II
atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Intermolecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the
bc
plane [centroid–centroid distance = 3.725 (3) Å] are present in the crystal structure.</description><subject>Metal-Organic Papers</subject><issn>1600-5368</issn><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNplkE1OwzAQhS0EoqVwAHZdtlINHtuJ3Q0SKgUqVbAA1pb_Qo2SpnICUnaciSWH4BCchERFCMRiNDPvzXyLh9AxkBMAIk7vICUkYakESjhMJdlB_U7Cnbb7a-6hg6p6IgRSQWEf9SijkjPO-2h-EUwsi-DKUTpJP1_fsAuFr1dNjumEdrsJmyYGF9Yef7wP6fBmOGmrdca2NDqvR4vF-BDtZTqv_NF3H6CHy_n97Bovb68Ws_MltoyzGlsthSNaEC9o5hMPRkyZkc448JRLyKjQNtHtScqE5hqkYQwy4qY-MdwaNkBnW-7m2RTeWb-uo87VJoZCx0aVOqi_zjqs1GP5olgCCYBoAbAF2FhWVfTZzy8Q1WWq_mXKvgC582oP</recordid><startdate>20121101</startdate><enddate>20121101</enddate><creator>Shirvan, Sadif A.</creator><creator>Haydari Dezfuli, Sara</creator><creator>Khazali, Fereydoon</creator><creator>Aghajeri, Manouchehr</creator><creator>Borsalani, Ali</creator><general>International Union of Crystallography</general><scope>AAYXX</scope><scope>CITATION</scope><scope>5PM</scope></search><sort><creationdate>20121101</creationdate><title>Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ 2 N , N ′)cobalt(II)</title><author>Shirvan, Sadif A. ; Haydari Dezfuli, Sara ; Khazali, Fereydoon ; Aghajeri, Manouchehr ; Borsalani, Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c343t-ca87d0a70e72fe5e1b793b8dbd1e2481f27ac5ad0a637a4a18b331f0d9e5b4cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Metal-Organic Papers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shirvan, Sadif A.</creatorcontrib><creatorcontrib>Haydari Dezfuli, Sara</creatorcontrib><creatorcontrib>Khazali, Fereydoon</creatorcontrib><creatorcontrib>Aghajeri, Manouchehr</creatorcontrib><creatorcontrib>Borsalani, Ali</creatorcontrib><collection>CrossRef</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shirvan, Sadif A.</au><au>Haydari Dezfuli, Sara</au><au>Khazali, Fereydoon</au><au>Aghajeri, Manouchehr</au><au>Borsalani, Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ 2 N , N ′)cobalt(II)</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><date>2012-11-01</date><risdate>2012</risdate><volume>68</volume><issue>11</issue><spage>m1363</spage><epage>m1363</epage><pages>m1363-m1363</pages><issn>1600-5368</issn><eissn>1600-5368</eissn><abstract>In the title compound, [CoBr
2
(C
12
H
12
N
2
)], the Co
II
atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Intermolecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the
bc
plane [centroid–centroid distance = 3.725 (3) Å] are present in the crystal structure.</abstract><pub>International Union of Crystallography</pub><pmid>23284344</pmid><doi>10.1107/S1600536812041980</doi><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1600-5368 |
| ispartof | Acta crystallographica. Section E, Structure reports online, 2012-11, Vol.68 (11), p.m1363-m1363 |
| issn | 1600-5368 1600-5368 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3515117 |
| source | DOAJ Directory of Open Access Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Metal-Organic Papers |
| title | Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ 2 N , N ′)cobalt(II) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T00%3A28%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmedcentral_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Dibromido(6,6%E2%80%B2-dimethyl-2,2%E2%80%B2-bipyridine-%CE%BA%202%20N%20,%20N%20%E2%80%B2)cobalt(II)&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Structure%20reports%20online&rft.au=Shirvan,%20Sadif%20A.&rft.date=2012-11-01&rft.volume=68&rft.issue=11&rft.spage=m1363&rft.epage=m1363&rft.pages=m1363-m1363&rft.issn=1600-5368&rft.eissn=1600-5368&rft_id=info:doi/10.1107/S1600536812041980&rft_dat=%3Cpubmedcentral_cross%3Epubmedcentral_primary_oai_pubmedcentral_nih_gov_3515117%3C/pubmedcentral_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/23284344&rfr_iscdi=true |