Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ 2 N , N ′)cobalt(II)
In the title compound, [CoBr 2 (C 12 H 12 N 2 )], the Co II atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Intermolecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-11, Vol.68 (11), p.m1363-m1363 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, [CoBr
2
(C
12
H
12
N
2
)], the Co
II
atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Intermolecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the
bc
plane [centroid–centroid distance = 3.725 (3) Å] are present in the crystal structure. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812041980 |