trans-Dichloridobis(4-nitro-aniline-κN(1))palladium(II)

In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro-aniline ligands and two Cl atoms in a trans arrangement. Inter-molecular N-H⋯Cl hydrogen bonds involving the amino groups and chloride anions le...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-11, Vol.68 (Pt 11), p.m1351-m1351
1. Verfasser: Feng, Tian-Jun
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro-aniline ligands and two Cl atoms in a trans arrangement. Inter-molecular N-H⋯Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N-H⋯O and N-H⋯Cl hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812042134