Di-μ-iodido-bis-[(dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate-κ(2)N,N')copper(I)]

In the centrosymmetric dinuclear title complex, [Cu(2)I(2)(C(22)H(16)N(2)O(4))(2)], the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate ligand and two symmetry-related I atoms, which act as bridges to a...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-06, Vol.68 (Pt 6), p.m756-m757
Hauptverfasser: Starosta, Radosław, Komarnicka, Urszula K, Nagaj, Justyna, Stokowa-Sołtys, Kamila, Bykowska, Aleksandra
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Sprache:eng
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Zusammenfassung:In the centrosymmetric dinuclear title complex, [Cu(2)I(2)(C(22)H(16)N(2)O(4))(2)], the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate ligand and two symmetry-related I atoms, which act as bridges to a symmetry-related Cu(I) atom. The distance between the Cu(I) atoms within the dinuclear unit is 2.6723 (11) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812020843