Cationic Palladium(II) Catalysis: C−H Activation/Suzuki−Miyaura Couplings at Room Temperature

Cationic palladium(II) catalyst realized facile C−H activation of aryl urea with arylboronic acids at room temperature. This reaction is extremely mild to carry out aromatic C−H activations through electrophilic substitution.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2010-04, Vol.132 (14), p.4978-4979
Hauptverfasser:	Nishikata, Takashi, Abela, Alexander R, Huang, Shenlin, Lipshutz, Bruce H
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Cations - chemistry Hydrocarbons, Aromatic - chemical synthesis Hydrocarbons, Aromatic - chemistry Molecular Structure Organometallic Compounds - chemistry Palladium - chemistry Temperature
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Cationic palladium(II) catalyst realized facile C−H activation of aryl urea with arylboronic acids at room temperature. This reaction is extremely mild to carry out aromatic C−H activations through electrophilic substitution.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja910973a